Yes, you can use fly ash of forest biomass as cement replacement in concrete. It is similar to rice husk ash, but have to analyse the chemical composition of that fly ash ... means how much silica or calcium is available. Rest particle size also matters. If its particle size is very small then can be used as cement replacement, if its size is large then can be used as fibrous material or fine aggregate replacement.
Ye you can use as long as it was tested for its freeze-thaw resistance. Because some ashes does not provide a suitable air-void system required for freeze-thaw resistance.