The reaction rate constant of Acetone with Hydroxyl radicals (*OH radicals) is 1.1 x 10^8 M-1.s-1.
Does anyone know the reaction rate constant of Acetone with Sulfate radicals (SO4*-)?
If you don't know the exact value, do you have any idea/ hint if it is faster or slower? And by what order of magnitude? 2 folds? 10 folds? 100 folds? 1000 folds?
Most data is contained in the J.Phys.Chem.Ref.Data series. This is probably in the edition associted with inorganic radicals. Structure relationship diagrams have been produced for other free radicals such as NO3 so maybe there is a similar one for SO4- in the literature.
Visit www.nist.gov database. the J.Phys.Chem.Ref.Data series are in this site.
Thank you for your replies. I have already checked these references and the work of Neta but unfortunately no details on Acetone. They include 1000s of compounds but acetone is not one of them.
Thanks.
Dear Murtaza,
I'm just curious whether you read this paper?
Where did you find this number: "It will be 6.0E8 M-1s-1?"
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