I want to prepare a unidirectional parallel porous structure with ionotropic gelation of sodium alginate. I tried it with sodium alginate solution and CaCl2 or CuSO4 electrolytes as many articles mentioned.

but unfortunately, the products were loose gels or they were not gel as i could not detach them from the mold to continue the process.

In other experiments, I add sodium alginate solution to the electrolyte solution or add the electrolyte to sodium alginate solution in various manners but the gelation did not occur at all.

I guess the G/M ratio and G distribution of alginate affect my work. but I don't know if it is probable that my alginates don't have any G block?!!

My alginate is food industrial grade.

Has storage conditions affected monomer distribution?

What is your advice about this?

thank you very much

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