Primero deberías de hacer pruebas de solvencia de tu polímero con distintos disolventes, ya que no todos los sólidos son solubles en todos los disolventes, y decidir según solubilidad. Vas a necesitar disolventes orgánicos si no es soluble en agua, y muchos de ellos son inflamables/tóxicos/carcinogénicos, etc.
I doubt that there would be any generic solvent to dissolve any polymer. If you are looking for a solvent of intermediate polarity like acetone and want to avoid chlorinated solvents a possible alternative would be methyl tetrahydrofurane.
An alternative is butanone (button-2-one) - this is similar to acetone, but has a much higher boiling point. It is often used for alkylations etc. It has a bp of 79-80 compared to 56 degrees of acetone.
Burdick & Jackson solvents are arranged in order of increasing polarity index, a relative measure of the degree of interaction of the solvent with various polar test solutes.
Apart from your desired solvent qualities ( non-flammability and low boiling point), the choice will be totally dependent on the family/ class which the polymer belongs. Based on the principal that 'like dissolves like, the attached document will provide you with good ideas on which solvent to use when a particular repeating unit of the polymer is involved.
I already tried Ethyl Acetate and nothing happened. I guess Butanone could be a good choice for the reasons you mention. Thank you all for your contributions!
N-methyl-2-pyrrolidone (NMP) can be used. It is a polar aprotic solvent and dissolves many polymers. It has high boiling point ( >200 degree centigrade) It is soluble in water and easy to dispose which is a great advantage during work up of reactions.
Typical organic solvents are usually flammable with exception of chloroform and other polyhalogenated hydrocarbons. Maybe halotan CHBrClCF3 would be suitable?
Thank you all for your contributions. The first assay shows that apparently MEK is a suitable option. It has dissolved main part of the polymer and it is less volatile than acetone, which is a good point. I am considering a mixture of IPA and 1,4-dioxane, since I have read it can be a good option too. I'll come back with more test results!
NMP (N-Methylpyrrolidine) can be used. It is a polar , water soluble solvent with high boiling point (about 202-204 degree centigrade). It dissolves many polymers easily. Of course like other organic compounds it is combustible but not highly inflammable like ether, acetone, ethyl acetate or benzene. It's self ignition temperature is about 250 degree. I think one can use it as solvent for polymers.