Is there a way/procedure to perfrom an esterfication reaction on free sterarate which is present as zinc-stearate in zinc-paste (zinc-stearate plus ESBO) and to quantifiy this newly formed ester using GC-MS (solvent injction)?
Ï guess the first step would be to check for literature on this ;-).
If there is not my best guess would be to:
1) hydrolyse the Zink complex by dissolving in methanol acidify mildely (1% acidic acid) dilute say 1:10 in water mix well keep over night
2) extract the stearic acid by shaking with e.g. n-hexane, phase separate (separation funnel), eventually dry and condense
3) add TMSH solution, wait an hour, inject analyse the methyl ester
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Nature 2010
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