A-site deficient 0.1BiScO3-BaTiO3 (BSBT) thin films were deposited on Pt/TiO2/SiO2/Si substrate by using PLD.
XPS results revealed that A-site vacancies increase with the increase of deposition temperature (510-550 C).
XRD analysis showed that the degree of (110)-texture also increases with the increase of deposition temperature or, in other words, (110)-texture increase with the increase of A-site vacancies.
It is noted that BSBT grows as a polycrystalline thin film with a random orientation at the same deposition temperature and substrate when stoichiometry is tightly controlled.
Li, D. Y., and J. A. Szpunar. "A Monte Carlo simulation approach to the texture formation during electrodeposition—I. The simulation model." Electrochimica acta 42, no. 1 (1997): 37-45.
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