What kind of mechanism do you postulate for platinum affecting the relaxivity of magnetite nanoparticles? Platinum (but not cisplatin) is paramagnetic (roughly comparable with manganese, which is used as MR contrast agent); so one should expect a certain relaxivity of platinum itself. FePt nanoparticles are superparamagnetic. Increasing the concentration of platinum (or of FePt particles) should therefore shorten the relaxation time of the solvent or of tissue. This effect should add to the relaxivity of magnetite.
I wouldn't expect any "more direct" influence of Pt to magnetite (but I may be wrong, of course), since magnetic properties are determined by the electronic structure of elements or compounds, and the electronic structure of the magnetite particles should not be modified signficantly by the presence of Pt outside the nanoparticles.
Thank you Olaf. I am clueless about whether it would affect at all. I was aware Pt is paramagnetic but was wondering if cisplatin would have the same effect as platinum, if it were in close proximity with MNPs.