Can someone please help with information on the thermodynamic or physical significance of the Freundlich constants K and 1/n in the equation x/m = KCe1/n? I am doing some experiments on adsorption of dye solution on activated carbon and the data fitted quite well to Freundlich isotherm. The plot of the logarithm of the Freundlich constant K against reciprocal of the temperature in Kelvin ( according to Van't Hoff's equation) was linear in a manner suggesting that it has some thermodynamic implications. Am I doing something stupid? Even the values of the exponential term 1/n change in a manner suggesting dependence on temperature. Is there any scientific basis for treating the Freunlich constant K as the equilibrium constant of adsorption of the dye on the hydrophobic sorbent? Any useful material will be appreciated too.