An aqueous unsaturated solution of CaCl2 at 32.1% w/w can provide 59% of relative humidity for the equilibrium atmosphere over the solution at 25 ºC. Concentration may be not as stable as it could be attained with some alternative saturated salt solution.
Reference:
R. H. Stokes, R. A. Robinson, "Standard Solutions for Humidity Control at 25° C", Ind. Eng. Chem., 1949, 41(9), pp. 2013–2013; or: John A. Dean (Ed.), Lange's Handbook of Chemistry, 15th ed., McGraw-Hill, 1999, p. 11.7.