The difference would depend in which way are coating. For example: If you use spin coating, u will get a flimsy structure. Also the form may change if you use heating in your coating.
TiO2 has three phases-Anatase, Rutile and Brookite. These are temperature dependent phases. Anatse is stable upto 500-700 degree C depending on structural morphology. Rutile is more stable phase. Also Anatase will change to Rutile after heating around 700-800 degree C. You can get mixture of both phases.