What are the functional groups are responsible for basicity of biomass derived carbon supports? I would appreciate if anyone provide some reference articles. Thanks
The functional groups that are responsible for the basicity of biomass-derived carbon supports are primarily nitrogen-containing groups, such as pyridinic, pyrrolic, and graphitic nitrogen. These nitrogen-containing groups can act as Lewis bases and can readily donate electrons to acids, making the carbon support basic. Other functional groups that may contribute to basicity include oxygen-containing groups, such as carboxylic and phenolic groups, as well as sulfur-containing groups.
Here are a few articles that discuss the basicity of biomass-derived carbon supports:
"Basicity of Nitrogen-Containing Carbon Materials Derived from Biomass: A Critical Review" by H. L. Wu and S. H. Chan (ChemSusChem, 2018).
"Basicity of Nitrogen-Containing Carbon Materials Prepared by Hydrothermal Carbonization of Lignocellulosic Biomass" by M. H. Y. Siddique, A. Mehta, and C. A. Grande (ACS Sustainable Chemistry & Engineering, 2019).
"Investigation of the Basicity and Surface Chemistry of Biomass-Derived Carbons" by K. L. Knoops, K. S. Walton, and P. J. Dauenhauer (Langmuir, 2016).
These articles provide a detailed analysis of the basicity of biomass-derived carbon supports and the specific functional groups responsible for their basic properties.