I looking forward to know how to specify the band gap alignment and band offsets of two layers 2D heterostructure semiconductor?
Can I determine the band alignment (type I or II) without using XPS or STM?
You can do this, depending on what semiconductors you have in the heterojunction. Read this please
https://www.tf.uni-kiel.de/matwis/amat/semi_en/kap_5/backbone/r5_3_1.html
You have to know the work function the semiconductors and the Fermi level position to align the bands.
SKPFM (Kelvin probe atomic force microscopy) can also be used to measure this, if you have a cross section, e.g. Article Quantitative Operando Visualization of the Energy Band Depth...
I agree with Valentin Bogatu.
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