We, the pedologists at the ICAR-NBSS&LUP, Nagpur while working for the last two decades to pinpoint the factors of organic carbon (OC) accumulation in Indian tropical soils, realized the extreme potential of smectite clay minerals in sequestering OC in Vertisols of western, central and southern peninsular region. Rate of OC accumulation in Vertisols (developed exclusively in the smectitic alluvium of the weathering Deccan basalt) shows an enhancement with the increase in mean annual rainfall (MAR) (Pal et al., 2009, the pdf attached). Non-sodic and non-saline smectite dominated Vertisols (Haplusterts) (with clay CEC > 80-100 cmol(P+)/kg based on NaOAc-NH4OAc method) with and without soil modifiers like Ca-zeolites and gypsum, show that soils in arid dry (AD) bio-climate has the least amount of SOC (0.5%) in the surface and 0.43 % as weighted mean (WM) value in the 0-1m soil profile. In semi-arid dry (SAD) it is 0.6 % and 0.44%, in semi-arid moist (SAM) it is 1.0 % and 0.78%, in sub-humid dry (SHD) it is 1.1% and 0.55%, in sub-humid moist (SHM) it is 1.1% and 0.67%. However, in humid tropical (HT) bio-climate, the Vertisols (Haplusterts) under agriculture show a little decline in SOC to 0.9% in the surface and 0.65 % as WM value in the first 1m of the soil profile. This SOC decline is apparently due to their lower clay CEC (~ 50 cmol (P+)/kg) as caused by the dominant presence of smectite – kaolinite interstratified minerals (Sm-K) alongside moderate amount of smectite. This mineral combination is in contrast to the exclusive presence of smectite like in soils of AD, SAD, SAM, SHD and SHM bio-climates.
It is interesting to note that even with Sm-K minerals and smectite (with clay CEC < 50 cmol (P+)/kg), zeolitic shrink-swell soils (Haplusterts) under forest cover in the HT climate of the Western Ghats and Satpura Range, qualify for Mollisols as per the US Taxonomy because these Mollisols (Vertic Haplustoll/ Argiudoll) contain 2-3 % OC in the surface and the OC as WM in the first 1m of the profile ranges from 0.94 to 1.6%. It is now clear that despite low content of clay smectite and in dominant presence of Sm-K mineral, shrink-swell soils are capable of accumulating substantial amount of OC due to favourable clay CEC along with profuse vegetative cover under abundant rainfall associated with cool winter temperature of few months and the presence of Ca-zeolites (Bhattacharyya et al, 2006, 2014, pdfs attached).
The above factors, however, cannot fully explain the huge SOC accumulation in kaolinite-hydroxy-interlayered vermiculite (K-HIV) dominated (with clay CEC around 11 – 22 cmol (P+)/kg, based on NH4OAc, pH 7 method) (Pal et al., 2014, the pdf attached) Ultisols and acidic Alfisols, developed on granite, granite-gneiss and sedimentary rocks under HT climate in the states of Kerala, North-Eastern Hill areas and Goa. These fairly to highly weathered HT soils contain 2- 5% OC in the surface and their WM value of OC in the first 1m of the profile ranges from 1.2 – 1.9 % (Pal et al., 2014, the pdf attached), which are comparable to and often more than that of the zeolitic Mollisols derived from the Deccan basalt (Bhattacharyya et al., 2006,2014). Presence of Ca-zeolites is an additional advantage as they are also capable of sequestering OC in soils by absorbing atmospheric CO2 (Pal et al., 2013, 2015, the pdf attached). Truly, it is an intriguing issue of OC sequestration in HT soils and thus, through this posting in RG, I urge my esteemed colleagues all over the world to help in identifying any additional factor other than those known hitherto that can explain the mechanism of OC enrichment in K-HIV dominated Ultisols and acidic Alfisols of Indian tropical humid climate.