Usually, if you have a very inhomogeneous liquid-to-vapor ratio in adjacent fluid inclusions, they were a product of necking down. Boiling will produce two families of fluid inclusions: liquid-rich and vapor-rich. In any case, if you perform microthermetry on these fluid inclusions you can use the beahviour of data to decipher between necking and boiling.
This is difficult to decide. The best way, if you don't have textural proofs of boiling (bladed calcite) i to start with a very accurate petrography, to classify the different typs of fluid inclusions as FIA's (fluid inclusion assemblages) in function of the position of the FI's (along growth zones, fractures), if they are primary, secondary, pseudosecondary... finally, to generate a map with the distribution of FI's and finally, to populate the map with Th's and Tmice (or salinities). With all this information, you can decide if boiling took place or not... you'll see if it make sense.