the parameter I am looking are at temperature, surface water temperature, precipitation, discharge rate, ph and dissolved oxygen for a data that spans 30 years in the region. What statistical analysis can be use to see causation possibilities between precipitation, air temperature and river discharge rate?
Adding to Francesco's comment, you may want to explore various lag times for your correlations. For example, correlate water-year river discharge with water-year precipitation from the same and prior years in a single multiple linear regression analysis. River discharge generally lags precipitation over various time scales; so explore various time lags for correlations between precipitation data and river discharge data; especially when looking at seasonal and shorter periods for river discharge.