Would you think of any copper complexes be able to exchange their ligands with N's in g-C3N4, in (aqueous, non-aqueous, or non-polar) solution or gas? For example, would there be any copper carbonyl stable enough to evaporate and transfer onto the g-C3N4? would the carbonyl ligand be exchanged with the N's in g-C3N4?
Some studies have focused on synthesizing Cu-g-C3N4 through adsorption or encapsulation of copper complexes in g-C3N4 network by putting a heteroatom between Cu and N (where Cu is not directly coordinated by N in the network).
see: [ 10.1039/C7CY00420F ]
Cu-doped g-C3N4 has also been synthesized through a one-pot synthesis method in which Cu atom is directly interacted with Nitrogen atom. For more information see: [ 10.1016/j.jssc.2015.04.027 ]
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