UV-Vis spectra of cystein cappid Ni nps in ethylene glycol have of plazmon band 360--420 nm (brown to deep black of nanoparticles) http://www.ncp.edu.pk/docs/iss/talks/Group_II/G2_D2_Dr_Nazar_Hussain_Kalawar.pdf
You are not synthesized nickel nanoparticles. This band absorption of substances with a benzene ring or another functional group.
Thanks Dear Yuri, but I did not use any capping agent yet this the first phase of the reaction I used Ni-ions precursor +NaBH4+NaOH+H2O only,kindly tell me what product give such band that give slight red shift from 206 to 222.4 with passages of time , any ways sir thank you so much for your answer ,I will wait for your next answer.