Yes, it will decompose at 300°C, but neat NaN3 decompose with explosion ( sodium nitride is not intermediate because less stable, it decompose ~ 360°K). Melting point of sodium is 98°C - so only fine aerosol of sodium droplets will appear in inert atmosphere. To suppress explosion, mixtures with inert supports are used. SiO2 is common; but some salts are also applicable (NaCl)
Yes, I am agree with Andrei Rogoza, Melting point of sodium is 98°C - so only fine aerosol of sodium droplets will appear in inert atmosphere. The sodium Liquid metal aerosol present in inert atmosphere and aerosol concentration depends upon sodium temperature and geometry of vessel. The sodium aerosol mass concentration in inert atmosphere is few 100mg/m3 to few g/m3 at sodium temperature 300 to 360°C.