Mixing of SWCNT and MWCNT with TiO2 and doping F into TiO2 cause an extension of the absorption towards the red shift in the spectra. This extension for F-TiO2, F-TiO2/MWCNT and F-TiO2/SWCNT on the rise, respectively.
After inspecting you absorbance curve one sees the addition of graphine to TiO2 and building a composite material, leads to appreciable absorption of light by the graphine
in a wide range of wavelength because the carbon black. So, the whole curve will be shifted upward causing the extrapolation of the absorbance edge to cut the x-axes at longer wavelengths.
So, it is because the absorption by the black graphine.