I would be thankful to you all for the  answer to my following curiosity: 

Magnetic resonance imaging (MRI) or NMR exploits the proton spin of H-atom in water (mostly). Protons' spins are polarized/excited with the static magnetic field. But why the magnetic field does not affect the electrons orbiting the nucleus of H-atoms? Why are electrons not affected? Is it the case of intrinsic spin quantum numbers or gyromagnetic ratio? I mean, what is the reason of exploitation of protons' spins (but not electrons' spins) H-atoms in MRI/NMR? 

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