I am seeing a mix of alkane and alkene in this aryl ketone clemmensen reduction. They come out as a single peak in HPLC, so separation isn't an option. Can anyone propose why I am seeing this mix (approx 1:1) of products, and offer a potential solution?

Ps. I have also tried Pd/C H2 hydrogenation and fail to see complete conversion after 5 days.

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