I know Nafion has been extensively used as a binder.
You might use a polymer binder (e.g. PVdF(poly(vinylidene fluoride))/) to fabricate the nanocomposite electrodes.
or use a binder-free supercapacitor electrode by direct growth of metal composite oxide nansostructures.
Thanks Shen-Ming Chen
What are their possible roles beside providing help in long term stability?
PVDF and PTFE are the best binder to be used for the supercapacitor
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