The internal resistance of my oscilloscope is 1 MOhm. It is large but still there is some current through the solar cell under test. Thus, I am not sure if I do not measure just the RC constant instead of the Voc decay due to the recombination of photogenerated charge carriers.
You are going to need a high input impedance voltage follower. But you must be careful about offset null voltage. I recommend you JFET or MOSFET input op.amp. Please glance figure.2 at the attached paper. I think It's going to be useful for you. Regards