I am attempting to analyze the significance of minor species within the framework of supersonic combustion inside a model combustor. Your insights on this topic would be greatly appreciated.
Hi, unfortunately I'm just a theoretician not involved in supersonic combustion. Please, find somebody else who is more experienced in this relation.
Regards,
IF
In peroxide combustion, the most common reactions that involve HO2 are:
1. HOOH+HOO→OH+O2+H2O
2. HOO+OH→O2+H2O
3. HOO+HOO→O2+HOOH
4. HOO+H2O→OH+HOOH
see this reference from Goddard: PNAS, 116 (37), 18202-18208
The reaction mechanism H2 + O2 includes hundreds reactions with known rate constants. It's a time consuming job to look through the data bases. Check NIST website.
For the beginning look at
https://www.google.com/url?sa=t&rct=j&q=&esrc=s&source=web&cd=&ved=2ahUKEwimjobMxaaCAxWkl2oFHbwDBos4MhAWegQIBhAB&url=https%3A%2F%2Fwww3.nd.edu%2F~powers%2Fame.60636%2Fbaulch2005.pdf&usg=AOvVaw1mdiNPHWmoHxgPMu9o0MfN&opi=89978449
Evaluated Kinetic Data for Combustion Modeling
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University of Notre Dame
https://www3.nd.edu › ame.60636 › baulch2005
by DL Baulch · 2005 · Cited by 822 — ... Chemical Kinetics of the IUPAC Physical Chemistry Division.
In the H2-O2 combustion system, the HO2 radical plays several significant roles:
HO2 radical is one of the intermediates important at lower temperatures in a premixed flame structure. Supersonic combustion occurs in diffusion mode and the temperature range is about 1000 K to 3000 K and residence times available for combustion will be about a millisecond. What matters is heat release and on this the peroxyl radical has little influence. To my mind it is a closed issue. You are welcome to pursue what may turn out to be not-so-significant subject. You might like to read some our publications in late nineties (you can see www.hsmukunda.in)
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