According to Einstein's definition of simultaneity, two events are simultaneous in a given system of reference, if they occur at the same time, as measured by clocks that have been synchronized using light signals. The determination of the time of arrival of one of those light signals has an uncertainty \delta t, depending on the corresponding distribution of frequencies, or energies of the corresponding photons. The assumption that an electron cannot be at the same time (simultaneously) in two different places is behind the difficulty to understand electron diffraction. Is simultaneity a macroscopic concept? Is time and duration, as a consequence, an emergent, and not a fundamental concept?