I have attached an image. Can you kindly explain what does it mean from the delocalization of P-orbital from the LUMO plot?
I have made a statement " From the LUMO plot it is seen that the overlap of p orbitals at the central porphyrin ring results in the formation of conjugate π-bonds in the structure leading to a diffused distorted cloud of electrons. "
Am i right?
Hello,
I would advise to reformulate it like this: From the LUMO plot it can be seen that it is mostly localized at the central ring with smaller or insignificant contributions from other rings.
Best regards,
Aleksey.
Hello,
I think you should check the orbitals coefficients.
According to HOMO, there are many atoms, ready, to the contribution in electron transmissions, while the LUMO shows localization around a small area.
Generally, I think there is no wrong.
Best regards,
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