I have digested 30mL of water in H2SO2 and the final volume is 100. After taking 5ml for distillation, the titration volume with HCL 0.01N for water sample was 1.7mL and for blank was 0.1mL.
Convert the titration to mg NH3--N and that is the amount of N in 5 mL of sample. Be sure to analyse some standards and factor in the recovery (if necessary).