The following are some ideas regarding battery chargers and charging methods that could be helpful to you
Charging Schemes
The charger has three key functions: Getting the charge into the battery (Charging), Optimising the charging rate (Stabilising), Knowing when to stop (Terminating)
The charging scheme is a combination of the charging and termination methods.
Charge Termination
Once a battery is fully charged, the charging current has to be dissipated somehow. The result is the generation of heat and gasses both of which are bad for batteries. The essence of good charging is to be able to detect when the reconstitution of the active chemicals is complete and to stop the charging process before any damage is done while at all times maintaining the cell temperature within its safe limits. Detecting this cut off point and terminating the charge is critical in preserving battery life. In the simplest of chargers this is when a predetermined upper voltage limit, often called the termination voltage has been reached. This is particularly important with fast chargers where the danger of overcharging is greater.
Safe Charging
If for any reason there is a risk of overcharging the battery, either from errors in determining the cut off point or from abuse this will normally be accompanied by a rise in temperature. Internal fault conditions within the battery or high ambient temperatures can also take a battery beyond its safe operating temperature limits. Elevated temperatures hasten the death of batteries and monitoring the cell temperature is a good way of detecting signs of trouble from a variety of causes. The temperature signal, or a resettable fuse, can be used to turn off or disconnect the charger when danger signs appear to avoid damaging the battery. This simple additional safety precaution is particularly important for high power batteries where the consequences of failure can be both serious and expensive.
Charging Times
During fast charging it is possible to pump electrical energy into the battery faster than the chemical process can react to it, with damaging results.
The chemical action cannot take place instantaneously and there will be a reaction gradient in the bulk of the electrolyte between the electrodes with the electrolyte nearest to the electrodes being converted or "charged" before the electrolyte further away. This is particularly noticeable in high capacity cells, which contain a large volume of electrolyte.
There are in fact at least three key processes involved in the cell chemical conversions. One is the "charge transfer", which is the actual chemical reaction taking place at the interface of the electrode with the electrolyte and this proceeds relatively quickly. The second is the "mass transport" or "diffusion" process in which the materials transformed in the charge transfer process are moved on from the electrode surface, making way for further materials to reach the electrode to take part in the transformation process. This is a relatively slow process which continues until all the materials have been transformed.
The charging process may also be subject to other significant effects whose reaction time should also be taken into account such as the "intercalation process" by which Lithium cells are charged in which Lithium ions are inserted into the crystal lattice of the host electrode. See also Lithium Plating due to excessive charging rates or charging at low temperatures.
All of these processes are also temperature dependent.
In addition, there may be other parasitic or side effects such as passivation of the electrodes, crystal formation and gas build up, which all affect charging times and efficiencies, but these may be relatively minor or infrequent, or may occur only during conditions of abuse. They are therefore not considered here.
The battery charging process, thus has at least three characteristic time constants associated with achieving complete conversion of the active chemicals which depend on both the chemicals employed and on the cell construction. The time constant associated with the charge transfer could be one minute or less, whereas the mass transport time constant can be as high as several hours or more in a large high capacity cell. This is one of the reasons why cells can deliver or accept very high pulse currents, but much lower continuous currents. (Another major factor is the heat dissipation involved). These phenomena are non linear and apply to the discharging process as well as to charging. There is thus a limit to the charge acceptance rate of the cell. Continuing to pump energy into the cell faster than the chemicals can react to the charge can cause local overcharge conditions including polarisation, overheating as well as unwanted chemical reactions, near to the electrodes thus damaging the cell. Fast charging forces up the rate of chemical reaction in the cell (as does fast discharging) and it may be necessary to allow "rest periods" during the charging process for the chemical actions to propagate throughout the bulk of the chemical mass in the cell and to stabilise at progressive levels of charge.
The following are some ideas regarding battery chargers and charging methods that could be helpful to you
Charging Schemes
The charger has three key functions: Getting the charge into the battery (Charging), Optimising the charging rate (Stabilising), Knowing when to stop (Terminating)
The charging scheme is a combination of the charging and termination methods.
Charge Termination
Once a battery is fully charged, the charging current has to be dissipated somehow. The result is the generation of heat and gasses both of which are bad for batteries. The essence of good charging is to be able to detect when the reconstitution of the active chemicals is complete and to stop the charging process before any damage is done while at all times maintaining the cell temperature within its safe limits. Detecting this cut off point and terminating the charge is critical in preserving battery life. In the simplest of chargers this is when a predetermined upper voltage limit, often called the termination voltage has been reached. This is particularly important with fast chargers where the danger of overcharging is greater.
Safe Charging
If for any reason there is a risk of overcharging the battery, either from errors in determining the cut off point or from abuse this will normally be accompanied by a rise in temperature. Internal fault conditions within the battery or high ambient temperatures can also take a battery beyond its safe operating temperature limits. Elevated temperatures hasten the death of batteries and monitoring the cell temperature is a good way of detecting signs of trouble from a variety of causes. The temperature signal, or a resettable fuse, can be used to turn off or disconnect the charger when danger signs appear to avoid damaging the battery. This simple additional safety precaution is particularly important for high power batteries where the consequences of failure can be both serious and expensive.
Charging Times
During fast charging it is possible to pump electrical energy into the battery faster than the chemical process can react to it, with damaging results.
The chemical action cannot take place instantaneously and there will be a reaction gradient in the bulk of the electrolyte between the electrodes with the electrolyte nearest to the electrodes being converted or "charged" before the electrolyte further away. This is particularly noticeable in high capacity cells, which contain a large volume of electrolyte.
There are in fact at least three key processes involved in the cell chemical conversions. One is the "charge transfer", which is the actual chemical reaction taking place at the interface of the electrode with the electrolyte and this proceeds relatively quickly. The second is the "mass transport" or "diffusion" process in which the materials transformed in the charge transfer process are moved on from the electrode surface, making way for further materials to reach the electrode to take part in the transformation process. This is a relatively slow process which continues until all the materials have been transformed.
The charging process may also be subject to other significant effects whose reaction time should also be taken into account such as the "intercalation process" by which Lithium cells are charged in which Lithium ions are inserted into the crystal lattice of the host electrode. See also Lithium Plating due to excessive charging rates or charging at low temperatures.
All of these processes are also temperature dependent.
In addition, there may be other parasitic or side effects such as passivation of the electrodes, crystal formation and gas build up, which all affect charging times and efficiencies, but these may be relatively minor or infrequent, or may occur only during conditions of abuse. They are therefore not considered here.
The battery charging process, thus has at least three characteristic time constants associated with achieving the complete conversion of the active chemicals which depend on both the chemicals employed and on the cell construction. The time constant associated with the charge transfer could be one minute or less, whereas the mass transport time constant can be as high as several hours or more in a large high capacity cell. This is one of the reasons why cells can deliver or accept very high pulse currents, but much lower continuous currents. (Another major factor is the heat dissipation involved). These phenomena are non linear and apply to the discharging process as well as to charging. There is thus a limit to the charge acceptance rate of the cell. Continuing to pump energy into the cell faster than the chemicals can react to the charge can cause local overcharge conditions, including polarization, overheating as well as unwanted chemical reactions, near to the electrodes thus damaging the cell. Fast charging forces up the rate of chemical reaction in the cell (as does fast discharging) and it may be necessary to allow "rest periods" during the charging process for the chemical actions to propagate throughout the bulk of the chemical mass in the cell and to stabilize at progressive levels of charge.