Boron has desirable effects when alloyed in small amounts (≈0.001 wt %) due to enhanced hardenability. When amount of boron exceeded >0.003 wt%, steel becomes brittle due to reduces hardenability and impact toughness.
I agree with David. Small amounts of B are beneficial to hardenability, but the Boron needs to be 'protected' from forming precipitates as soluble B enhances hardenability. Too much soluble B can increase HAZ hardness, thus lowering toughness. Excessive B will precipitate, leading to brittleness.
Please keep in mind that extra boron contents may lead to formation of Boron Carbide (B4C) through Carbothermic process, which is Covalent-bonded, high temperature, hard, brittle and non soluble ceramic and may precipitate in grain boundaries and leads to increase in hardness besides falling the toughness and impact resistance.