I am working on oxidative stress in fish.
If your work involves consideration for ROS and radicals like carbon monoxide and carbonate radical, then this may be the order of preference:
PBS >> HEPES > Tris
Tris is worst because it contains a rather reactive primary amine.
PBS has virtually no target groups for ROS to attack.
You can take a look at the methods section of this book (Part V, Chapter 32):
http://onlinelibrary.wiley.com/book/10.1002/9781444345988
thanks a lot....
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