When using the XRD diffraction technique, what happens to the density of dislocation When undergo metal alloy to the plastic deformation compared with normal conditions? Are the density increase or decrease and why?
Dear Dr. Basheer, Your question is not well defined! However, we can make the following statements:
The dislocation multiplication ( increase in dislocation density) occurs during the plastic deformation through the activation of the various dislocation sources such as Frank-Read Sources, large precipitate (inclusions) particles having sufficiently big sizes that can't be cut through by the moving dislocations but rather go around and leaving dislocation loops. There is relationship between the dislocation density and the plastic shear strain, which is given by d= do+ a x Gamapm, , where do is initial (grown in) dislocation density [metals: about 108 cm/cm3, and ionic and covalent crystals 103 cm/cm3 ] a is a constant ( f metals: about equal to 108 cm/cm3), m is about =1.
The applied tensile stress) required to induced plastic flow [ which corresponds to about 0.2% elongation for the most FCC metals and alloys ) is known as the elastic limit or yield stress. In the elastic region dislocation density variations are almost negligible, one can only talk about their rearrangements if the temperature is sufficiently high enough to allow dislocations to climb and cross slip to form polygonization or low angle grain boundaries etc. Best regards.
There are various annihilation mechanisms, which reduces the dislocation density in the elastic region such as two edge dislocations having opposite Burgers vector sliding in the same slip planes, or through the non- conservative climb and plus the slide motion reaching the same slip plane and combine with opposite one. Surfaces and grain boundaries also act as sinks for the dislocations. The straight screw dislocation can change its slip plane by gliding (cross slip), which doesn't require any conservative motion since its Burgers vector is parallel to the dislocation line. Therefore annihilation of screw dislocations of opposite sign is very effective mechanism.
From a mechanical point of view, real processing involves multi-axial loading. Depending on the instantaneous nature of the stress tensor at a point (e.g. compressive, tensile) density of dislocation can increase or reduce. You need more details about the process and loading to interpret/understand the changes.
Dear Dr. Khoddam, the crystal dislocations can only recognize the follow stress acting on their slip or glide planes. The shear stress acting on the dislocation line is given by n . Sigma. b where n is the surface normal vector associated with the slip or glide plane , and b is the unit vector along the Burgers vector B of the dislocation line. Force acting may be written as F= n . Gigma. B, B is the Burgers vector. Gigma is the local stress tensor. This is a local stress tensor as the name implies will change along dislocation line as well as during the motion of the mobile dislocations. For the static loading it only depends on the space variable.
In the case of non conservative motion (i.e., climb of edge dislocations) which is thermally activated process involving vacancies and/or interstitials, The stress normal to the slip plane of an edge dislocation line F= n . Gigma. n is also a driving force for the climb process, which also involves short range diffusion of vacancies or interstitials depending open the sign of edge dislocation.
I agree with all your explanations. The only thing that I can add is: when a multi-axial loading at a point arises, the compressive and tensile stress components can be transformed into shear components along the dislocation plane using the Mohre Circle and therefore even positive or negative stress tensor components can contribute into how the dislocation density changes.
Dear Dr. Khoddam, What you are saying orally is perfectly alright. I put that into the mathematical format using the dyadic representation of the second order tensors, precisely. Sigma in my comment is a stress tensor given in dyadic format. What happens when you have a pure hydrostatic stress, which is represented by p [1], which yields n.p[1] = n p, where [1] is unit tensor, and the result is n p. That tells us that there is no shear stress acting on the given slip plane ( actually there is no shear in any plane) , where n is the unit surface normal vector . p can be negative or positive.
Similarly if we have a screw dislocation in isotropic media then this only interacts with the deviatoric part of the local stress tensor not the dilatation part.. The main reason; the strain field generated by the screw dislocation has zero trace (no diagonal parts). On the hand Edge dislocation has dilatation as well as deviatoric parts, can interact with any type of stress system. But F= n . p [1]. B, = 0, it can't sllp under the pure hydrostatic pressure since n.B= 0.
I can't agree with you more on the special cases you discussed, but my point is about a general case of multi-axial loading which typically results in development of shear components along the slip planes.
Dear Dr. Khoddam, Your are definitely right having disagree with me by putting the special cases on the table, which screws up everything that the general argument claims for. But I am as a theoretician, always interesting with the special cases, singularities etc., which are mostly overlooked , and are too tough deal with analytically. Best Regards
It is really depend on the the type of deformation, strain content and the property of the material. Mainly the dislocation density increases by increase the amount of deformation. Nevertheless in some cases, for example strain reversal is happened and the density is reduced.Also, in severe plastic deformation methods after a certain amount of strain the dislocation density is remain the same and reduced due to recovery . Please read one of my publications which is attached to this email.
Article Processing twining induced plasticity steel through simple s...
If the strain reversal takes place in the elastic range (not necessarily in the linear stress-strain connection range) the mobile dislocation density reduces if you assume dislocation mechanism of elastic deformation. Actually one has no hysteresis in the elastic strain reversal for the infinitely slow loading and unloading. If the deformation invıolves point defect movements from one stable configuration to another one, like the case of the anelastic relaxation phenomena in BCC metals and alloys where interstitial O, C and N moves from one octahedral site to another octahedral site according to the change in direction of the applied stress field. Then the strain reversal shows hysteresis with a dissipation of energy. By the same way, the dislocations pinned down by the point defects can show cyclic anelastic strain changes with the dissipation of energy driven by the applied oscillator stress systems.
dear`sir please share all the information as loading condition etc., i guess your ques. might be : what is effect on dislocation under XRD and without XRD.
There are certainly other techniques for measuring such as TEM and AFM, but the important question what happen to the dislocation density of the metal alloy after exposure to an external load and get the plast deformation. I guss we can arrange a new question about how to measure the density of dislocation for metal alloy by using other techniques without XRD diffraction. Thank you very much for the posts value of my friends and thanks to you also.