What does it mean if the constant n of the Sips (Langmuir-Freundlich) model is greater than 1?
Note that in my adsorption data when n(sips) is fixed at 1 the Qmax of Sips = Qmax of Langumir!
Dear Dhirar Ben Salem, let me cite, please: "For n > 1,
Eq. (3) may be identified as describing a cooperative reaction
between a sorption site and n sorbate molecules, such that b is
the equilibrium constant of this reaction. In this case, Eq. (3) coincides
with the Hill model characterizing cooperative interactions
of ligand molecules with a macromolecule (Cantor and Schimmel,
1980)."Article Sorption Interactions of Organic Compounds with Soils Affect...
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