Respected scholar, I have synthesized bare silver nanoparticles using sodium borohydride reduction at room temperature and measured their UV-Vis absorption spectrum. The spectrum showed two distinct peaks - a sharp peak at 260nm and a broader, lower intensity peak at 411nm. What could account for the presence of these two separate surface plasmon resonance signals?

Any insights you could provide regarding the origin and assignment of multiple SPR peaks would be greatly appreciated.

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