Various methods such as transient hot wire method and microscale beam deflection method are available but i want to know the theory behind these methods especially transient hot wire method.
Measuring thermal conductivity of liquid is really difficult from practical point of view.
By the way what kind of liquid. For liquid with high viscosity like glycerol KD 2 is a way to go, but for Liquid like water with low viscosity KD 2 is not a solution in my view even a lot of paper published with using that device.
I recommend built your own device based on transient method.
Hot wire technique is the most accepted and used method. For low liquids amounts you can use photopyroelectric method. This is a photothermal technique suitable for thermal diffusivity, D, and thermal effusivity, e, measurement. Thermal conductivity can be calculated as k=eD^1/2
I use steady-state method with a coaxial-cylinder cell with deviations lower than 1 %. You can download some literature in my profile. What kind of liquids do you want to measure?
As somebody is interested in: We start a Ring Robin Test with an oil, a coolant, a PCM and a low pressure refrigerant in Germany with help of the Society of Thermal Analysis (GEFTA) currently.
For liquids, if you require low uncertainty, there is only one method the THW (Assael M.J., Nieto de Castro C.A., Roder H.M., and Wakeham W.A., Chapter 7, "Transient Methods for Thermal Conductivity", in "Experimental Thermodynamics. Vol. III. Measurement of the Transport Properties of Fluids", Eds. Nagashima A., Sengers G.V., and Wakeham W.A., Blackwell Scientific Publications, p.161 - 195 (1991). ISBN: 0-632-029978 ). This is known since 1991. Do not reinvent the wheel. THW will give you an absolute uncertainty of +/-0.5%. I have been invloved with THW for 35 years now. Just make sure you employ the technique properly. I strongly advise you to avoid any unexpensive commercial instruments unless 10% is good for you. If you read Tertsinidou et al (2015) Int. J. Thermophys. you will see the effect of bad application of THW and also of commercial needle probe insstruments. In conclusion, if you are going to do it, do it RIGHT, no simplifications...
I would like to measure thermal conductivity of various refrigerants such as R134a and R410A and i would also like to measure the thermal conductivity of refrigerant oil mixture.
So according to you, THW is the most appropriate method to be used for measuring thermal conductivity of liquids. I will have a look at the references mentioned by you.
Prof. Marc J. Assael made the measurements for the refriegrants very exactly. You can trust his measurements. We both (Marc in Thessaloniki, Greece and I in Dresden, Germany) can execute this measurements with the same accuracy. I think it depends on price and time.
I think and I believe Marc has the same opinion: If you never have done a thermal conductivity measurement of liquids before, than don't think a minute about constructing a measurement equipment by yourself. It is connected by many many problems that you never thought about before and the price of the equipment is much higher than service measurements will be.
Kind regards and please contact Marc and me for service measurements.
Thermal conductivity of the liquid can be measured using KD2 pro thermal property analyzer (Decagon, Canada). The probe sensor used for these measurements are of 6 cm in length and 1.3 mm in diameter
Thermal conductivity of the liquid can be measured using KD2 pro thermal property analyzer (Decagon, Canada). The probe sensor used for these measurements are of 6 cm in length and 1.3 mm in diameter
Thermal conductivity of the liquid can be measured using KD2 pro thermal property analyzer (Decagon, Canada). The probe sensor used for these measurements are of 6 cm in length and 1.3 mm in diameter
Dear Mr. Nair, KD2 Pro can be use to measure the thermal conductivity of liquid samples. However, for low viscosity liquids like water utmost caution is needed during measurements to avoid inaccuracies due to natural convection. I also suggest you consult Prof. Asseal to help you as Dr. Feja recommended. All the best for your research
There are mainly two methods to determine the thermal conductivity of the materials. Such as steady state method, transient method and Laser flash methods. Under steady state method, transient method technique is most commonly used to determine the thermal conductivity of the low conductivity materials. General objective of conductivity laboratory experiment is to apply the concepts of heat flow to measure the thermal conductivity of various materials. Temperature is a measure of the kinetic energy of the random motion of molecules with a material.
1. Steady state methods(Searle's bar method, Lees' disc method)