Here please find a series of references for the straightforward synthesis of benzothiophene (extracted from ChemBrain IXL (http://neuronix.ch/chembrain)):
Comprehensive Heterocyclic Chemistry, Bird, C. W.; Cheeseman, G. W. H., Eds.; Pergamon: New York, (1984); Vol. 4.
Iddon, B.; Scrowston, R. M., Adv. Heterocycl. Chem., (1970) 11, 177.
Ple, P. A.; Marnett, L. J., J. Heterocycl. Chem., (1988) 25, 1271.
Gallagher, P.; Owton, W. M., Synth. Commun., (1989) 19, 2731.
Dann, O.; Kokorudz, M., Chem. Ber., (1958) 91, 172.
Rao, D. S.; Tilak, B. D., J. Sci. Ind. Res., Sect. B, (1959) 18, 77.
Titus, R. L.; Choi, M.; Hutt, M. P., J. Heterocycl. Chem., (1967) 4, 651.
synthesis of benzothiophene the starting material is 2-chloroethyl thiophenol which can be cyclized by heating under alkaline condition to get desired product.