according your published paper as co-author, I am surprised that you didn 't post a CORRECT question. Your question is too vague and obscure. In order to help you:
Please start GOOGLE SCHOLAR and not GOOGLE and you will find a lot of hits concerning your question.
Your question is too vague and must be reformulated. P. e. do you mean XRAY fluorescence method or UV-VIS fluorescence method .
What do you mean with physical uses.
What a kind of herbal plants?? are they the same as in your publications?
Please note that your are working with VERY LOW concentration of trace elements . If you chemicals are DIRTY (e.g. not pure enough) , you 'll see perhaps the fluorescence of your impurities besides the trace elements.
an abstract from google scholar:
1. Introduction
Traditionally, herbs are universally applied in popular and folk
medicine, and play an important role in the general state of health
in many populations. They are usually not biologically aggressive
and do not have severe side effects. The therapeutic activity of
herbs is associated with the content of biologically active organic
compounds of varying structures and remedial powers such as
alkaloids, tannins, oils, or vitamins. In addition to pharmacologically
active substances, there is a growing interest in their chemical
composition because of ongoing developments in nutrition and
biochemical surveying and mineral prospecting (Kalny, Fijałek,
Daszczuk, & Ostapczuk, 2007).
Raw plant materials are derived from sources subject to action
of natural biogeochemical environment and may be easily contaminated
with pesticides, microbial contaminants, heavy metals,
chemical toxins and adulterated with orthodox drugs during
growth and processing. Herbs constitute an important link in the
transfer of trace elements from soil to man. The level of essential
elements in plants varies, and content being affected by the geochemical
characteristics of a soil and by the ability of plants to
selectively accumulate some of these elements. Bioavailability of
the elements depends on the nature of their association with the
constituents of a soil. Plants readily assimilate elements through
the roots. Additional sources of elements for plants are rainfall,
atmospheric dusts, plant protection agents, and fertilizers that
can be absorbed through the leaf blades (Łozak, Sołtyk, Ostapczuk,
& Fijałek 2002). Therefore, it is important to use combined regimes
for studies on medicinal herbs and analysis. Due to the importance
of the mineral and trace elements present in herbs, several studies
have been carried out to determine their levels by using graphite
furnace atomic absorption spectrometry (GF-AAS) (Kalny et al.,
What do you mean by physical uses? Please clarify....but..........
if you want to know what is the significance of trace elemental composition in herbal medicines then some of these points are helpful:
1. Plants contain many inorganic constituents including heavy toxic metals. So, elemental analysis is useful for deciding the proper dose of herbal extract or formulation. Excessive consumption of these will cause some disorders in humans.
2. Also many of them are useful for formation of secondary compounds such as alkaloids, glycosides and others which are attributed for medicinal properties of these plants.
3. Elemental analysis is sometime useful for management of some kind of environmental contaminants or pollutants with phytoremediation technology.
4. Elemental composition is also helpful to draw the information on plant metabolism as most of these are co-factor of variety of enzymes.