Domain walls or boundaries are expected to form when a discrete symmetry is broken spontaneously.
REF:
Y. B. Zeldovich, I. Y. Kobzarev and L. B. Okun, Zh. Eksp. Teor. Fiz. 67 (1974) 3
[Sov. Phys. JETP 40 (1974) 1]; T. W. B. Kibble, J. Phys. A9, 1387 (1976); A. Vilenkin, Phys. Rept. 121 (1985) 263