To my belief, there is no such built-in function in MATLAB for designing UKF.
A good read : Wan, Eric A., and Rudolph Van Der Merwe. "The unscented Kalman filter for nonlinear estimation." Adaptive Systems for Signal Processing, Communications, and Control Symposium 2000. AS-SPCC. The IEEE 2000. Ieee, 2000.
You use the UKF when the state transition and observation models—that is, the predict and update functions "f" and "g"are highly non-linear, the extended Kalman filter can give particularly poor performance). I dont know why you want to use UKF for RC system(linear) but if you want to do anyway: