When a light ray is incident on the media interface at an angle greater than the critical angle how do we know that the ray would be reflected?

Is there any mathematical proof?

Let me illustrate:

Let critical angle,a=45d then n2/n1=sin(45)=1/root(2)

if now i=60 then angle r must be 60d because of TIR but.....

sini/sinr=n2/n1 => sin60/sinr=1/root(2)=> r!=60.

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