Dynamic light scattering (DLS) is used in Molecular Weight determination in some situations. Please search relevant literature to see if this technique can be applied in the Molecular Weight regime you are interested in measuring.
Oligomers of what? If they are soluble in, say, methanol, you should definitely do MS. Mass of 1000 is reasonably low, so electrospray should work fine if whatever you're working with can be ionized in one way or another.