The surfactant selective electrode has been used extensively to
study the binding of ionic surfactants to charged and neutral
macromolecules. Can anyone please suggest an alternate methods regarding this.
Tandrima Banerjee
In addition to the selective electrode method, surfactant binding to neutral and charged molecules can be studied by
1. nephelometry (solubility)
2. UV-visible spectroscopy
3. Small angle neutron scattering
4. Isothermal titration calorimetry
Tam K.C., Wyn-Jones E. // Chem Soc Rev 2006. 35. 693-709.
Musabekov K.B., Zhubanov B.A., Izmailova V.N., Summ B.D., Interfacial layers of polyelectrolytes: (Synthetic polymers) Science, Alma-Ata, 1987.
Efimova A.A., Sybachin A.V., Chvalun S.N., Kulebyakina A.I., Kozlova E.V., Yaroslavov A.A. // Polym Sci Ser B+ 2015. 57. 140-144
The binding of polyesters and surfactants is mediated by water. Therefore, it is necessary to "monitor" the change in the state of water. Therefore, new methods are needed
1. the effect of enthalpy-entropy compensation
2. determination of the change in the electron density of water
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