Rotational constants (GHZ): 0.1722105 0.0637054 0.0501274 Standard basis: 6-311++G(d,p) (5D, 7F) There are 907 symmetry adapted cartesian basis functions of A symmetry. There are 874 symmetry adapted basis functions of A symmetry. 874 basis functions, 1382 primitive gaussians, 907 cartesian basis functions 121 alpha electrons 120 beta electrons nuclear repulsion energy 3359.0762438298 Hartrees. NAtoms= 53 NActive= 53 NUniq= 53 SFac= 1.00D+00 NAtFMM= 60 NAOKFM=F Big=F Integral buffers will be 262144 words long. Raffenetti 2 integral format. Two-electron integral symmetry is turned on. One-electron integrals computed using PRISM. NBasis= 874 RedAO= T EigKep= 1.51D-06 NBF= 874 NBsUse= 865 1.00D-06 EigRej= 9.94D-07 NBFU= 865 Initial guess from the checkpoint file: "C:\g16w\PE.chk" B after Tr= 0.000000 0.000000 0.000000 Rot= 0.999890 -0.012343 0.002602 -0.007743 Ang= -1.70 deg. Initial guess = 0.0000 = 0.0000 = 0.5000 = 0.7712 S= 0.5105 ExpMin= 3.60D-02 ExpMax= 9.34D+04 ExpMxC= 3.17D+03 IAcc=3 IRadAn= 5 AccDes= 0.00D+00 Harris functional with IExCor= 402 and IRadAn= 5 diagonalized for initial guess. HarFok: IExCor= 402 AccDes= 0.00D+00 IRadAn= 5 IDoV= 1 UseB2=F ITyADJ=14 ICtDFT= 3500011 ScaDFX= 1.000000 1.000000 1.000000 1.000000 FoFCou: FMM=F IPFlag= 0 FMFlag= 100000 FMFlg1= 0 NFxFlg= 0 DoJE=T BraDBF=F KetDBF=T FulRan=T wScrn= 0.000000 ICntrl= 500 IOpCl= 0 I1Cent= 200000004 NGrid= 0 NMat0= 1 NMatS0= 1 NMatT0= 0 NMatD0= 1 NMtDS0= 0 NMtDT0= 0 Petite list used in FoFCou. Requested convergence on RMS density matrix=1.00D-08 within 128 cycles. Requested convergence on MAX density matrix=1.00D-06. Requested convergence on energy=1.00D-06. No special actions if energy rises. Restarting incremental Fock formation.

need help please what is the problem