I am performing CV with pencil graphite electrodes as the working electrode, Pt as the counter and Ag/AgCl as the reference electrode. I notice that the current peaks shift in the 1st to the 10th cycle and the 10th to the 20th cycle. But then on the 30th and 40th cycle they almost stay the same followed by another jump in the peak for the 50th cycle.
I cannot understand the reason for this phenomena