Is there any chance of any kind of reaction between gamma butyro lactone (GBL) with Triethylamine (TEA)? In a very old paper I found that butenolides dimerize in presence of base, though GBL is a saturated butenolides.
More information can be helpful... some batches of Et3N can have minute quantities of some impurities, these can react with GBL. If your solvent is, say MeOH (:-)...) lactone ring may be opening, etc. etc... so, details do matter.