For example: some oxide materials like SnO2, and other conducting oxides based on the availability of the chemical can be deposited which can exhibit semiconducting properties.
But such films are mostly polycrystalline in nature, grannular and rough.
Carrier Mobility will be very low, and carrier concentration control depends on annealing, annealing temp., and annealing ambient depending on the semiconductor material composition which is being deposited by the spray pyrolysis technique.