This is a somewhat complicated question. Imines do interact with CO2, allowing molecules with imine functional groups to be useful for CO2 physisorption applications. However, the actual chemical interaction between the two species is more nuanced. Recent studies suggest that a switch from primarily physical adsorption to chemical requires significant amine density on the surface of the material of study, and that will vary depending on the amino functional group utilized. Here is a good starting paper for your studies!