there are lot of interesting studies which suggests that too much of clustering of economies in urban areas can leads to dis-agglomeration of economies. please read "Critical commentary. Informality in space :Understanding Agglomeration economies duuring economic development", by Ann Moreno Murray. Available on website.
Maybe the paper Population Distribution, Urbanization, Internal Migration and Development: An International Perspective published by the UN could help you. Is available on internet.
Thanks for the research leads, particularly Porter (1997)- did not realize he did work on urbanism as well, more familiar with his books and HBR articles.