As you may know the most common method will be to use the implicit Euler method for solving an ODE. You may also look into the central difference method or the midpoint method.
You have a non-linear system of equations in two variables. You will need to write a function that returns the derivatives of theta and psi, in terms of theta, psi and the other parameters. If you have access to MATLAB, I'd recommend using ode15s. If not, the scipy package in python also provides a library of ode solvers that is very easy to use. Look for scipy.integrate.odeint.