I have performed CV at different scan rate. now i want to make this kind of graph as attached in origin. anyone can please help how to plot this graph?
There are many ways how to plot such a graph. You could use Python, Matlab, Gnuplot, Excel, or whatever is your preferred tool.
Personally, I like TikZ and pgfplots, which can easily produce such images. Also, since the image in TikZ is described as a text source code, it is easy to edit and to include in your LaTeX source. The documentation can be found here: https://ctan.org/pkg/pgfplots?lang=en .
The stand-alone example and the output are attached. You should be able to achieve desired output by tweaking the example.