I have been trying for a while to excite a molecule from a triplet ground state surface to a singlet excited state using Gaussian09 using the following input keywords.

#cam-b3lyp/gen td(singlet,nstates=10,root=1) scrf(smd, read, solvent=n,n-DiMethylFormamide)

triplet O2

0 3

8 25.136529024 28.339914299 -0.193692832

8 26.017258738 29.165728406 -0.344116694

O 0

6-31+G**

****

Everytime I have landed on a triplet excited state rather than a singlet surface.

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